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Chemical Structure| 27126-76-7 Chemical Structure| 27126-76-7
Chemical Structure| 27126-76-7

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Product Details of [Hydroxy(tosyloxy)iodo]benzene

CAS No. :27126-76-7
Formula : C13H13IO4S
M.W : 392.21
SMILES Code : CC1=CC=C(S(=O)(OI(C2=CC=CC=C2)O)=O)C=C1
MDL No. :MFCD00011547
InChI Key :LRIUKPUCKCECPT-UHFFFAOYSA-N
Pubchem ID :325434

Safety of [Hydroxy(tosyloxy)iodo]benzene

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [Hydroxy(tosyloxy)iodo]benzene

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 27126-76-7 ]

[ 27126-76-7 ] Synthesis Path-Downstream   1~17

  • 2
  • [ 27126-76-7 ]
  • [ 3728-43-6 ]
  • [ 73177-95-4 ]
YieldReaction ConditionsOperation in experiment
35% In ethanol; acetonitrile; Petroleum ether; EXAMPLE 7 Reaction of p-Trimethylsilyltoluene with HTOB (1.64 g of HTOB, 0.01 mol) p-trimethylsilyltoluene was added to a slurry of 3.92 g, 0.01 mol of HTOB in CH3 CN (40 ml) at room temperature. An immediate yellow color formed in the mixture. The slurry was slowly heated with stirring and when a clear solution resulted, it was placed on a steam bath and brought to reflux for four hours. The orange brown solution was then removed from heat and poured into a beaker to evaporate. The residue was washed with ether and finally dissolved in a small volume of EtOH and treated with petroleum ether. On standing, a total of 1.32 g of the p-tolylphenyliodonium p-toluenesulfonate was obtained as tan crystals; mp 153-5, yield 35%. PMR(methanol-d4), δ2.30, s(6H, p-tolyl and tosylmethyl); 7.08-8.3 m(13H, aromatic). Analysis: Calculated for C20 H18 ISO3: %C, 51.62; H, 3.90; I, 27.28. Found: C, 50.91; H, 4.03, I, 27.03.
  • 4
  • [ 27126-76-7 ]
  • [ 629-54-9 ]
  • [ 116749-32-7 ]
  • 5
  • [ 1620-55-9 ]
  • [ 27126-76-7 ]
  • [ 35779-40-9 ]
  • Toluene-4-sulfonic acid 2-oxo-2-phenyl-1-pyridin-4-yl-ethyl ester [ No CAS ]
  • 6
  • [ 27126-76-7 ]
  • [ 34907-53-4 ]
  • [ 3976-35-0 ]
  • 7
  • [ 64611-67-2 ]
  • [ 27126-76-7 ]
  • [ 56177-37-8 ]
  • 8
  • [ 27126-76-7 ]
  • [ 3839-35-8 ]
  • 9
  • [ 20628-07-3 ]
  • [ 27126-76-7 ]
  • [ 1023921-83-6 ]
  • 10
  • [ 13031-43-1 ]
  • [ 27126-76-7 ]
  • [ 1023921-59-6 ]
  • 13
  • [ 27126-76-7 ]
  • [ 19230-50-3 ]
  • 5-nitro-2-[hydroxy(tosyloxy)iodo]benzoic acid [ No CAS ]
  • 14
  • [ 27126-76-7 ]
  • [ 13421-00-6 ]
  • mesityl-5-chlorobenzocarboxy-2-iodonium tosylate [ No CAS ]
  • 15
  • [ 27126-76-7 ]
  • [ 13421-00-6 ]
  • 5-chloro-2-[hydroxy(tosyloxy)iodo]benzoic acid [ No CAS ]
  • 16
  • [ 27126-76-7 ]
  • [ 57002-01-4 ]
  • (E)-(2-cyclohexylvinyl)(phenyl)iodonium tosylate [ No CAS ]
  • 17
  • [ 4139-61-1 ]
  • [ 27126-76-7 ]
  • 6-bromo-4-hydroxy-2-oxo-2H-chromen-3-yl 4-methylbenzenesulfonate [ No CAS ]
 

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